Modern Organonickel Chemistry
Organonickel chemistry plays an increasingly important role in organic chemistry, and interest in this topic is now just as keen as in organopalladium chemistry. While there are numerous, very successful books on the latter, a book specializing in organonickel chemistry is long overdue.
Edited by one of the leading experts in the field, this volume covers the many discoveries made over the past 30 years, and previously scattered throughout the literature. Active researchers working at the forefront of organonickel chemistry provide a comprehensive review of the topic, including cross-coupling reactions, asymmetric synthesis and heterogeneous catalysis reaction types.
A must-have for both organometallic chemists and synthetic organic chemists.
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1 Introductory Guide to Organonickel Chemistry
2 Nickelcatalyzed Crosscoupling Reactions
3 Reaction of Alkenes and Allyl Alcohol Derivatives
4 Reaction of Alkynes
5 Reaction of Dienes and Allenes
6 Cyclooligomerization and Cycloisomerization of Alkenes and Alkynes
Άλλες εκδόσεις - Προβολή όλων
active aldehydes alkenes alkenyl alkyl alkynes allene allylic Angew aryl asymmetric b-hydrogen elimination benzene bromide butadiene carbon carboxylic acid Catal catalytic cycle Chem chemistry chiral CO2Et CO2H CO2Me compounds conjugate addition coordination coupling reaction cross-coupling reaction cyclization cyclooligomerization cyclotrimerization diene dimer double bond electronic electrophiles enantio-differentiating enantioselectivity enolate enones equiv ester Et2Zn ethylene formed Grignard reagents halides heterogeneous homoallylation hydrogenation hydrovinylation i-Pr insertion intermediate ketones ligand Me2Zn methyl mixture molecules Ni-catalyzed Ni(II nickel catalysts nickel complex nickel-catalyzed nucleophilic olefin orbitals Organomet Organometallics oxidative addition p-allylnickel palladium Ph Ph phosphine phosphine ligands PPh2 PPh3 Pr Pr presence proceeds provides Raney reactivity reacts reductive elimination regioselectivity Sato shown in Eq shown in Scheme species stereoselectivity steric substrates synthesis tartaric acid temperature Tetrahedron Lett tion toluene transition metals transmetallation undergoes Yamamoto yield
Σελίδα xiv - JST, 4-1-8 Honcho Kawaguchi, Saitama, Japan Nanoporous carbons with both micropores and meso- or macropores were synthesized by a SiC>2 colloidal crystal-templating process. The SiC>2 opal templates exclusively contributed to the formation of meso- and macropores in carbons. The electrical...