Inorganic Chemistry in Focus IIIGerd Meyer, Dieter Naumann, Lars Wesemann John Wiley & Sons, 13 Δεκ 2006 - 375 σελίδες Metal clusters are on the brink between molecules and nanoparticles in size. With molecular, nano-scale, metallic as well as non-metallic aspects, metal clusters are a growing, interdisciplinary field with numerous potential applications in chemistry, catalysis, materials and nanotechnology. This third volume in the series of hot topics from inorganic chemistry covers all recent developments in the field of metal clusters, with some 20 contributions providing an in-depth view. The result is a unique perspective, illustrating all facets of this interdisciplinary area: * Inter-electron Repulsion and Irregularities in the Chemistry of Transition Series * Stereochemical Activity of Lone Pairs in Heavier Main Group Element Compounds * How Close to Close Packing? * Forty-Five Years of Praseodymium Diiodide * Centered Zirconium Clusters * Titanium Niobium Oxychlorides * Trinuclear Molybdenum and Tungsten Cluster Chalcogenides * Current State of (B,C,N)-Compounds of Calcium and Lanthanum * Ternary Phases of Lithium with Main-Group and Late-Transition Metals * Polar Intermetallics and Zintl Phases along the Zintl Border * Rare Earth Zintl Phases * Structure-Property Relationships in Intermetallics * Ternary and Quaternary Niobium Arsenide Zintl Phases * The Building Block Approach to Understanding Main-Group-Metal Complex Structures * Cation-Deficient Quaternary Thiospinels * A New Class of Hybrid Materials via Salt Inclusion Synthesis * Layered Perrhenate and Vanadate Hybrid Solids * Hydrogen Bonding in Metal Halides * Syntheses and Catalytic Properties of Titanium Nitride Nanoparticles * Solventless Thermolysis * New Potential Scintillation Materials in Borophosphate Systems. With its didactical emphasis, this volume addresses a wide readership, such that both students and specialists will profit from the expert contributions. |
Περιεχόμενα
| 1 | |
| 15 | |
3 How Close to Close Packing? | 29 |
4 Fortyfive Years of Praseodymium Diiodide PrI2 | 45 |
5 Centered Zirconium Clusters Mixedhalide Systems | 61 |
6 Titanium Niobium Oxychlorides Ligand Combination Strategy for the Preparation of Lowdimensional Metal Cluster Materials | 79 |
7 Trinuclear Molybdenum and Tungsten Cluster Chalcogenides From Solid State to Molecular Materials | 105 |
8 Current State on BCN Compounds of Calcium and Lanthanum | 121 |
13 Ternary and Quaternary Niobium Arsenide Zintl Phases | 195 |
14 The Buildingblock Approach to Understanding Maingroupmetal Complex Structures More than just Attempting to Hew Blocks with a Razor | 209 |
15 Cationdeficient Quaternary Thiospinels | 225 |
16 A New Class of Hybrid Materials via Saltinclusion Synthesis | 239 |
17 Layered Perrhenate and Vanadate Hybrid Solids On the Utility of Structural Relationships | 251 |
18 Hydrogen Bonding in Metal Halides Lattice Effects and Electronic Distortions | 267 |
19 Syntheses and Catalytic Properties of Titanium Nitride Nanoparticles | 279 |
20 Solventless Thermolysis A Possible Bridge Between Crystal Structure and Nanosynthesis? | 295 |
9 Compositional Structural and Bonding Variations in Ternary Phases of Lithium with Maingroup and Latetransition Elements | 141 |
10 Polar Intermetallics and Zintl Phases along the Zintl Border | 157 |
11 Rareearth Zintl Phases Novel Magnetic and Electronic Properties | 173 |
12 Understanding Structureforming Factors and Theoryguided Exploration of StructureProperty Relationships in Intermetallics | 183 |
21 New Potential Scintillation Materials in Borophosphate Systems | 305 |
| 325 | |
Άλλες εκδόσεις - Προβολή όλων
Inorganic Chemistry in Focus III Gerd Meyer,Dieter Naumann,Lars Wesemann Δεν υπάρχει διαθέσιμη προεπισκόπηση - 2006 |
Inorganic Chemistry in Focus III Gerd Meyer,Dieter Naumann,Lars Wesemann Δεν υπάρχει διαθέσιμη προεπισκόπηση - 2006 |
Inorganic Chemistry in Focus III Gerd Meyer,Dieter Naumann,Lars Wesemann Δεν υπάρχει διαθέσιμη προεπισκόπηση - 2006 |
Συχνά εμφανιζόμενοι όροι και φράσεις
Acta Crystallogr alkali Allg Alloys Compd Angew anions Anorg anti-bonding atoms band bridging cations chains chalcogen Chem chemical chloride close packing cluster chemistry cluster compounds cluster unit complex compounds containing coordination covalent crystal structure cubic decomposition density dimers distances distorted elements energy example Fermi level formation formula framework halide high-temperature hybrid hydrogen bonding Inorg interactions intermetallics ionic ions J.D. Corbett Lachgar lanthanide lattice layers ligands lithium lone pair M.G. Kanatzidis magnetic materials Meyer molecular NaAlH4 niobium niobium oxychloride nitride nitridoborates observed octahedral orbital oxygen parameter Phys polyhedra powders praseodymium precursor PrI2 PrI2-IV properties quaternary rare-earth metal reaction salt salt-inclusion sample Schnering Sevov shown in Fig Solid State Chem solid-state space group stability struc structure types studies surface area synthesis temperature ternary tetrahedral thiospinels tion titanium titanium nitride transition metals transition-metal ture unit cell X-ray Zintl phases
Δημοφιλή αποσπάσματα
Σελίδα xx - State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai 200050, China Keywords: Composite, Fracture toughness, Spark plasma sintering (SPS) Abstract.
Σελίδα xxii - Department of Chemistry and Biochemistry University of Notre Dame Notre Dame, IN 46556...
Σελίδα xxii - Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou...
Σελίδα xxi - Department of Chemistry, University of California, One Shields Avenue, Davis, CA 95616 ABSTRACT A laser driven electron x-ray source (LEXS) using a high repetition rate, terawatt laser system is described.