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PREFACE.

IN venturing to offer to the public, and more particu larly to the female sex, an introduction to Chemistry, the author, herself a woman, conceives that some explanation may be required; and she feels it the more necessary to apologize for the present undertaking, as her knowledge of the subject is but recent, and as she can have no real claims to the title of chemist.

On attending for the first time experimental lectures, the author found it almost impossible to derive any clear or satisfactory information from the rapid demonstrations which are usually, and perhaps necessarily, crowded into popular courses of this kind. But frequent opportunities having afterwards occurred of conversing with a friend on the subject of chemistry, and of repeating a variety of experiments, she became better acquainted with the principles of that science, and began to feel highly interested in its pursuit. It was then that she perceived, in attending the excellent lectures delivered at the Royal Institution, by the present Professor of Chemistry, the great advantage which her previous knowledge of the subject, slight as it was, gave her over others who had not enjoyed the same means of private instruction. Every fact or experiment attracted her attention, and served to explain some theory to which she was not a total stranger; and she had the gratification to find that the numerous and elegant illustrations, for which that school is so much distinguished, seldom failed to produce on her mind the effect for which they were intended.

Hence it was natural to infer, that familiar conversation was, in studies of this kind, a most useful auxiliary source of information; and more especially to the female sex, whose education is seldom calculated

to prepare their minds for abstract ideas, or scientific language.

As however, there are but few women who have access to this mode of instruction; and as the author was not acquainted with any book that could prove a substitute for it, she thought that it might be useful for beginners, as well as satisfactory to herself, to trace the steps by which she had acquired her little stock of chemical knowledge, and to record, in the form of dialogue, those ideas which she had first derived from conversation.

But to do this with sufficient method, and to fix upon a mode of arrangement, was an object of some difficulty. After much hesitation, and a degree of embarrassment, which, probably, the most competent chemical writers have often felt in common with the most superficial, a mode of division was adopted, which, though the most natural, does not always admit of being strictly pursued-it is that of treating first of the simplest bodies, and then gradually rising to the most intricate compounds.

It is not the author's intention to enter into a minute vindication of this plan. But whatever may be its advantages or inconveniences, the method adopted in this work is such, that a young pupil, who should occasionally recur to it, with a view to procure information on particular subjects, might often find it obscure or unintelligible; for its various parts are so connected with each other as to form an uninterrupted chain of facts and reasonings, which will appear sufficiently clear and consistent to those only who may have patience to go through the whole work, or have previously devoted some attention to the subject.

It will no doubt, be observed, that in the course of these Conversations, remarks are often introduced, which appear much too acute for the young pupils, by whom they are supposed to be made. Of this fault the author is fully aware. But in order to avoid it, it would have been necessary either to omit a variety of useful illustrations, or to submit to such minute explanations, and frequent repetitions, as would have render

ed the work tedious, and therefore less suited to its intended purpose.

In writing these pages, the author was more than once checked in her progress by the apprehension that such an attempt might be considered by some, either as unsuited to the ordinary pursuits of her sex, or ill justified by her own recent and imperfect knowledge of the subject. But on the one hand, she felt encouraged by the establishment of those public institutions, open to both sexes, for the dissemination of philosophical knowledge, which clearly prove that the general opinion no longer excludes women from an acquaintance with the elements of science; and on the other, she flattered herself that whilst the impressions made upon her mind, by the wonders of Nature, studied in this new point of view, were still fresh and strong, she might perhaps succeed the better in communicating to others the sentiments she herself experienced.

The reader will soon perceive, in perusing this work, that he is often supposed to have previously acquired some slight knowledge of natural philosophy, a circumstance indeed, which appears very desirable. The author's original intention was to commence this work by a small tract, explaining, on a plan analogous to this, the most essential rudiments of that science. This idea she has since abandoned; but the manuscript was ready, and might perhaps, have been printed at some future period, had not an elementary work of a similar description, under the title of "Scientific Dialogues," been pointed out to her, which, on a rapid perusal, she thought very ingenious, and well calculated to answer its intended object.

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CONNEXION between Chemistry and Natural Philoso-
phy.-Improved State of modern Chemistry.-Its
Use in the Arts.-The general Objects of Chemistry.
-Definition of Elementary Bodies.-Definition of
Decomposition.-Integrant and Constituent Parti-
cles.-Distinction between Simple and Compound
Bodies. Classification of Simple Bodies.-Of Che-
mical Affinity, or Attraction of Composition.-Ex-
amples of Composition and Decomposition.

CONVERSATION II.

ON LIGHT AND HEAT.

38

Light and Heat capable of being separated.-Dr. Her-
schel's Experiments.-Phosphorescence.-Of Calo-
ric. Its two Modifications.-Free Caloric.-Of the
three different States of Bodies, solid, fluid, and æri-
form.-Dilatation of solid Bodies.-Pyrometer.-
Dilatation of Fluids.-Thermometer.-Dilatation of
Elastic Fluids.-Air Thermometer.-Equal Diffusion
of Caloric.-Cold a Negative Quality-Professor
Prevost's Theory of the Radiation of Heat-Pro-
fessor Pictet's experiments on the Reflection of Heat.
-Mr. Leslie's Experiments on the Radiation of Heat.

CONVERSATION III.

CONTINUATION OF THE SUBJECT.

Page

61

Of the different Power of Bodies to conduct Heat.—At-
tempt to account for this Power.-Count Rumford's
Theory of the non-conducting Power of Fluids.-
Phenomena of Boiling.-Of Solution in general.-
Solvent Power of Water.-Difference between Solu-
tion and Mixture.-Solvent Power of Caloric.-Of
Clouds, Rain, Dr. Wells' theory of Dew, Evapora
tion, &c.-Influence of Atmospherical Pressure on
Evaporation.-Ignition.

CONVERSATION IV.

ON COMBINED CALORIC, COMPREHENDING

HEAT AND LATENT HEAT.

SPECIFIC

88

Of Specific Heat.-Of the different Capacities of Bo-
dies for Heat.-Specific Heat not perceptible by the
Senses. How to be ascertained.—Of Latent Heat.
-Distinction between Latent and Specific Heat.-
Phenomena attending the Melting of Ice and the
Formation of Vapour.-Phenomena attending the
Formation of Ice, and the Condensation of Elastic
Fluids. Instances of Condensation, and consequent
Disengagement of Heat, produced by Mixtures, by
the Slakeing of Lime.-General Remarks on Latent
Heat.-Explanation of the Phenomena of Ether boil-
ing, and Water freezing at the same Temperature.-
Of the Production of Cold by Evaporation.-Calo-
rimeter. Meteorological Remarks.

CONVERSATION V.

ON THE CHEMICAL AGENCIES OF ELECTRICITY. 107

Of Positive and Negative Electricity.-Galvani's Dis-
coveries. Voltaic Battery.-Electrical Machine.-
Theory of Voltaic Excitement.

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