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BY THE ORIGINAL EDITOR OF THE ENCYCLOPAEDIA METROPOLITANA,
ASSISTED BY EMIN ENT PROFESSIONAL AND Other GENTLEMEN.
IN TWENTY-TWO VOLUMES.
PRINTED FOR THOMASTEGG, 73, CHEAPSIDE;
SOLD BY N. HAILES, PiccADILLY: E. WILSON, Roy AL Exchange: J.
MASON, city Roap ;
GAS. Goth. and Swed. gasa, to ferment, a term first commonly used by Van Helmont for fluids of an aériform character. GAs. The various gaseous bodies have been enumerated, and their properties explained, in that department of chemistry, to which they peculiarly belong; and we now propose to direct the attention of our readers to one of the most important practical applications of gaseous chemistry, in the illumination of buildings, and even large cities, by carbureted hydrogen gas. The producing from coal an aériform fluid, which could be distributed at pleasure in every direction, for the purpose of economical illumination, has justly been ranked amongst the greatest benefits which the science and enterprise of this country have conferred on mankind. That coal evolves a permanently elastic and inflammable aériform fluid, seems first to have been experimentally ascertained by the Rev. Dr. Clayton, and a brief account of his discovery is published in the Philosophical Transactions for the year 1739. The following is an extract from his paper:- I got some coal, and distilled it in a retort in an open fire. At first there came over only phlegm, afterwards a black oil, and then likewise a spirit arose, which I could no ways condense; but it forced my lute or broke my glasses. Once when it had forced my lute, coming close thereto, in order to try to repair it, I observed that the spirit which issued from it caught fire at the flame of the candle, and continued burning with violence, as it issued out in a stream, which I blew out and lighted again alternately for several times. I then had a mind to try if I could save any of this spirit, in order to which, I took a turbinated receiver, and putting a candle to the pipe of the receiver, whilst the spirit arose, I observed that it catched flame, and continued burning at the end of the pipe, though you could not discern what fed the flame. I then blew it out, and lighted it again several times; after which I fixed a bladder, squeezed and void of air, to the pipe of the receiver. The oil and phlegm descended into the receiver, but the spirit, still ascending, blew up the bladder. I then filled a good many bladders therewith, and might have filled an inconceivable number more, for the spirit continued to rise for several hours, and filled the bladders almost as fast as a man could have blown them with his mouth; and yet the quantity of coals distilled was inconsiderable, * I kept this spirit in the bladders a considerable time, and endeavoured several ways to condense it, but in vain. And when I had a mind to divert strangers or friends, I have frequently taken one of these bladders, and pricking a hole therein with a pin, and compressing Vol. X-PART I.
gently the bladder near the flame of a candle till it once took fire, it would then continue flaming till all the spirit was compressed out of the bladder, which was the more surprising, because no one could discern any difference in the appearance between these bladders, and those which are filled with common air. “But then I found that this spirit must be kept in good thick bladders, as in |. of an ox, or the like; for if I filled calves' bladders therewith, it would lose its inflammability in twentyfour hours, though the bladders became not relaxed at all.' But the application of the gas thus generated to the purposes of economical illumination is of much more recent date, and the merit of introducing it is principally due to Mr. Murdoch, whose observations upon the subject are published in the Philosophical Transactions for 1808. He first tried it in Cornwall, in the year 1792; and afterwards, in 1798, established an apparatus upon a more extended scale at Boulton and Watt's foundry at Birmingham; and it was there that the first public display of gas lights was made in 1802, upon the occasion of the rejoicings for peace. These, however, were but imperfect trials, when compared with that made in 1805 at Messrs. Phillips and Lee's cotton mills at Manchester; and upon the results of which, all subsequent procedures, with regard to gas lighting, may be said to be founded. The whole cotton mill, and many adjacent buildings, were illuminated with coal gas, to the exclusion of lamps, candles, and other sources of artificial light. Nearly 1000 burners of different forms were employed; and the light produced was estimated equal to that of 2500 well managed candles of six to the pound. The most important and curious part of Mr. Murdoch's statement relates to the cost of the two modes of lighting (namely, by gas and candles) per annum. The cost of the coal, used to furnish the gas, amounting annually to 110 tons, was £125. Forty tons of coals to heat the retort £20, and the interest of capital sunk, with due allowance for accidents and repairs, £550. From the joint amount of these items must be deducted the value of seventy tons of coke, at 1s. 4d. per cwt., amounting to £93, which reduces the total annual expense to £602; while that of candles to give the same light would amount to £2000. Such was the flattering result of the first trial of gas illumination upon a tolerably extensive scale. In regard to its efficacy, we are informed by Mr. Murdoch, that the peculiar softness and clearness of the light, with its almost unvarying intensity, brought it into great favor with the work people; and its being free from * inconvenience of sparks, and the frequent necessity of snuffing, are circumstances of material importance, as tending to diminish the hazard from fire, to which cotton mills are so much exposed. When Mr. Lee was examined by Mr. Brougham, in 1809, before a committee of the house of commons, against the Gas-light and Coke Company's bill, his evidence was then equally favorable. He said, it gave no disagreeable smell; and when questioned as to the goodness and purity of the light, ‘I burn it,' said he, “every night in my own house, instead of thirty pairs of candles.’ He further added, that he found it perfectly wholesome, and that it was never complained of either in his own dwelling-house, or in the mill. The president and council of the Royal Society proved the high opinion which they entertained of the value and importance of Mr. Murdoch's communication, on the employment of the gas from coal for the purpose of illumination, by adjudging to him count Rumford's gold and silver medals. We are indebted to Dr. Henry, of Manchester, for some valuable researches concerning the composition of the aëriform products of several varieties of coal. He has pointed out the various composition of the gas at different periods
of the distillation, and has shown the important .
influence of the circumstances under which the coal is distilled, upon the proportion of gas yielded, and its fitness for the o: of illumination. This fact attracted the notice of Mr. Clegg, the engineer of the Gas-light Company, who has founded upon it several ingenious improvements in the construction of the retorts employed at the Westminster gas works. Coal in large heaps, and gradually heated, affords less gas, and more water and tar, than when it is extended over a considerable surface, and suddenly brought to a red heat. It is also very advantageous to dry the coal before its introduction into the retort. In a small gas apparatus, erected in the laboratory of the Royal Institution, it was found that 4 lbs. of good Newcastle coal, introduced into the retort previously heated red in a shallow iron pan, may be made to afford a produce of from twenty to twenty-six cubic feet of gas, consisting of 8 Olefiant gas. 72 Carbureted hydrogen. 13 Carbonic oxide and hydrogen. 4 Carbonic acid. 3 Sulphureted hydrogen. 100 The carbonic acid and sulphureted hydrogen are separated by the lime in the purifiers. The same quantity of coal introduced into the cold retort, and gradually heated, afforded only twenty-two cubic feet of gas, consisting of 5 Olefiant gas. 70 Carbureted hydrogen. 18 Carbonic oxide and hydrogen. 6 Carbonic acid. 1 Sulphureted hydrogen.
The specific gravity of the former gas, that of air being E 1000, was - 560, and of the latter = 555: the fitness of gases for the purposes of illuminating is, generally speaking, directly as their specific gravity. These experiments lead to the conclusion, that a chaldron of good Wallsend Newcastle coals would afford from 17,000 to 20,000 cubical feet of gas, but the process of distillation, as now carried on in the large establishments for lighting the metropolis, seldom affords a larger average produce than 12,000 cubical feet. There can, however, be little doubt that, by improvements in the construction and management of the retorts, the highest of the above averages might be procured; and calculating upon this produce of gas, and upon the other substances yielded by the operation, we obtain a curious and striking result. The average value in London of a chaldron of the best Newcastle coals is £3. The value of the products of its distillation is as follows:–
From the value of products must, of course, be deducted, the value of the common coal employed in the furnaces for heating the retorts, amounting to about five chaldrons for every fiveand-twenty chaldrons submitted to distillation, and the expense incurred by wear and tear, with the wages of the laborers, and lastly, the interest upon capital. Mr. Murdoch's estimate, already quoted, will be found pretty accurate upon these heads. The tar, is frequently employed for the production of gas, either by mixing it with small coal in the retorts, or by passing it through a red hot tube. Every pound yields between seventeen and eighteen cubic feet, containing from fifteen to twenty per cent. of olefiant gas. When, therefore, it has been cleansed by lime, it burns with a very brilliant flame, and is a most improving addition to the common gas. Wigan and Cannel coal yield the best and largest propo of gas for the purposes of illumination, ut it is seldom it can be employed on account of its high price. The burners, or tubes whence the gas issues for combustion, may be infinitely and tastefully varied. The varieties commonly employed are the bat's-wing burner, and the Argand burner. The former consists of a brass tube having a slit at its extremity about a quarter of an inch long and one-fortieth of an inch wide. The latter is composed of two concentric brass tubes, about two inches long, closed at bottom by a ring of brass, and at the top by one of steel, perforated with sixteen or eighteen holes, of one-thirtieth of an inch in diameter. The gas enters the cavity between the tubes, and issues from the circular row of apertures, where it is inflamed, and hav