The Inorganic Chemistry of Materials: How to Make Things out of Elements

Εξώφυλλο
Springer Science & Business Media, 31 Οκτ 1998 - 392 σελίδες
P.J. van der Put offers students an original introduction to materials chemistry that integrates the full range of inorganic chemistry. Technologists who need specific chemical facts to manipulate matter will also find this work invaluable as an easy-to-use reference. The text includes practical subjects of immediate use for materials such as bonding, morphogenesis, and design that more orthodox materials science volumes often leave out.
 

Περιεχόμενα

INTRODUCTION
xiii
12 The Periodic Table
2
Structure and Bonding
7
14 Chemical Change
15
15 Relations to Other Monodisciplines
18
16 The Use of Models
22
Exercises
26
References
27
64 Heterogeneous Catalysis
200
65 Growth of Crystalline Solids from Liquids
202
66 Converting Solids by Reaction with a Gaseous Reactant
204
67 Chemical Vapor Deposition
205
671 Operational Aspects and Equipment
207
672 Physical Chemistry of Chemical Vapor Deposition
208
673 The Pyrolytic Regime
210
674 Powder Synthesis
215

THE CHEMICAL BOND
29
22 Valence Electrons on Atoms and Interaction with Light
32
222 Interaction with Light
37
Molecular Orbital and Valence Bond Models
42
24 The Coordinative Bond in Complexes
49
25 Bonding in Ionic Compounds
54
26 The Miedema Model for Intermetallics
56
Electronegativity Equalization
61
28 Linnetts Localized Electron Model for Molecules
66
29 Johnsons Interstitial Electron Model for Metals
70
210 The Phlogiston Model
74
Exercises
82
References
83
INORGANIC MOLECULES
85
32 Complexes and Their Chemistry
88
321 Ligand Exchange
90
322 Redox Reactions
96
33 Molecules with Covalent Bonds
99
34 Inorganic Polymers
103
Exercises
107
References
108
STRUCTURAL SOLID STATE CHEMISTRY
109
42 Amorphous Solids and Icosahedral Phases
111
421 Glass
114
422 Glass Ceramics
117
423 QuasiCrystals or Icosahedral Phases
118
43 Boron and Borides
119
432 Metal Borides
121
433 Compounds of Boron with Nonmetallic Elements
124
44 Carbides and Nitrides
126
45 Oxides
129
452 Functional Ceramics
134
46 intermetallics
140
47 Intrinsic Properties
143
471 Electron Conductivity
144
472 Dielectric Properties
147
473 Ion Conductivity
149
475 Mechanical Properties
151
476 Optical Properties
152
477 Chemical Properties
155
Exercises
162
References
163
SOLID STATE REACTIONS
165
53 Kinetics of Solid State Reactions
169
54 Measuring Solid State Reaction Kinetics
174
55 The Chemistry of Ceramics and Sintering
175
551 Physical Solid State Sintering
176
552 LiquidPhase Physical Sintering
184
553 Reactive Sintering
185
Exercises
187
THE CHEMISTRY OF INORGANIC SURFACES
189
62 Physical Properties of Inorganic Solid Surfaces
193
63 Inorganic Colloids
195
675 The Catalytic Regime
218
676 Diffusion Limitation in the Dialytic Regime
225
677 Morphology Control
228
68 HighTemperature Corrosion
232
69 Surface Modification by Immobilization of Molecules
235
Exercises
237
References
238
INORGANIC MORPHOGENESIS
241
72 Extrinsic Properties of Materials
250
73 Fractal Dimensions
252
74 Simulations of ReactionDiffusion Processes Using Cellular Automata
257
75 The Chemistry of Fractal Distributions
261
752 Reactions on Fractal Surfaces
265
Exercises
268
SYNTHESIS OF INORGANIC MATERIALS
271
82 Solid State Reactions
280
83 Synthesis from Liquids
282
832 Liquid Salts as Solvents
284
833 Hydrothermal Processes
289
834 SolGel Method
291
84 Gas Phase Techniques
295
842 Physical Vapor Deposition
298
843 Chemical Vapor Deposition
300
844 Plasma Synthesis
310
Exercises
313
References
314
THE DESIGN OF INORGANIC MATERIALS
317
92 Requirements and Constraints
320
93 Combination Properties of Composites
324
931 Sum Properties
325
932 Product Properties
327
933 Morphology
328
94 Functional Materials
329
941 Thermistors
331
942 Varistors
333
943 Active Materials
334
95 Fabrication of Composites
338
Exercises
340
References
342
INORGANIC PHYSICAL CHEMISTRY
343
102 Equilibrium Thermodynamics
344
103 Defect Chemistry
352
Intrinsic Defect Concentrations
354
Extrinsic Defect Concentrations
355
Gas Equilibria
356
7034 Defect Reactions
360
104 Diffusion in Solids
366
105 A Note on Diffusion Coefficients
375
Exercises
377
References
378
INDEX
379
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