The Inorganic Chemistry of Materials: How to Make Things out of ElementsSpringer Science & Business Media, 31 Οκτ 1998 - 392 σελίδες P.J. van der Put offers students an original introduction to materials chemistry that integrates the full range of inorganic chemistry. Technologists who need specific chemical facts to manipulate matter will also find this work invaluable as an easy-to-use reference. The text includes practical subjects of immediate use for materials such as bonding, morphogenesis, and design that more orthodox materials science volumes often leave out. |
Περιεχόμενα
INTRODUCTION | xiii |
12 The Periodic Table | 2 |
Structure and Bonding | 7 |
14 Chemical Change | 15 |
15 Relations to Other Monodisciplines | 18 |
16 The Use of Models | 22 |
Exercises | 26 |
References | 27 |
64 Heterogeneous Catalysis | 200 |
65 Growth of Crystalline Solids from Liquids | 202 |
66 Converting Solids by Reaction with a Gaseous Reactant | 204 |
67 Chemical Vapor Deposition | 205 |
671 Operational Aspects and Equipment | 207 |
672 Physical Chemistry of Chemical Vapor Deposition | 208 |
673 The Pyrolytic Regime | 210 |
674 Powder Synthesis | 215 |
THE CHEMICAL BOND | 29 |
22 Valence Electrons on Atoms and Interaction with Light | 32 |
222 Interaction with Light | 37 |
Molecular Orbital and Valence Bond Models | 42 |
24 The Coordinative Bond in Complexes | 49 |
25 Bonding in Ionic Compounds | 54 |
26 The Miedema Model for Intermetallics | 56 |
Electronegativity Equalization | 61 |
28 Linnetts Localized Electron Model for Molecules | 66 |
29 Johnsons Interstitial Electron Model for Metals | 70 |
210 The Phlogiston Model | 74 |
Exercises | 82 |
References | 83 |
INORGANIC MOLECULES | 85 |
32 Complexes and Their Chemistry | 88 |
321 Ligand Exchange | 90 |
322 Redox Reactions | 96 |
33 Molecules with Covalent Bonds | 99 |
34 Inorganic Polymers | 103 |
Exercises | 107 |
References | 108 |
STRUCTURAL SOLID STATE CHEMISTRY | 109 |
42 Amorphous Solids and Icosahedral Phases | 111 |
421 Glass | 114 |
422 Glass Ceramics | 117 |
423 QuasiCrystals or Icosahedral Phases | 118 |
43 Boron and Borides | 119 |
432 Metal Borides | 121 |
433 Compounds of Boron with Nonmetallic Elements | 124 |
44 Carbides and Nitrides | 126 |
45 Oxides | 129 |
452 Functional Ceramics | 134 |
46 intermetallics | 140 |
47 Intrinsic Properties | 143 |
471 Electron Conductivity | 144 |
472 Dielectric Properties | 147 |
473 Ion Conductivity | 149 |
475 Mechanical Properties | 151 |
476 Optical Properties | 152 |
477 Chemical Properties | 155 |
Exercises | 162 |
References | 163 |
SOLID STATE REACTIONS | 165 |
53 Kinetics of Solid State Reactions | 169 |
54 Measuring Solid State Reaction Kinetics | 174 |
55 The Chemistry of Ceramics and Sintering | 175 |
551 Physical Solid State Sintering | 176 |
552 LiquidPhase Physical Sintering | 184 |
553 Reactive Sintering | 185 |
Exercises | 187 |
THE CHEMISTRY OF INORGANIC SURFACES | 189 |
62 Physical Properties of Inorganic Solid Surfaces | 193 |
63 Inorganic Colloids | 195 |
675 The Catalytic Regime | 218 |
676 Diffusion Limitation in the Dialytic Regime | 225 |
677 Morphology Control | 228 |
68 HighTemperature Corrosion | 232 |
69 Surface Modification by Immobilization of Molecules | 235 |
Exercises | 237 |
References | 238 |
INORGANIC MORPHOGENESIS | 241 |
72 Extrinsic Properties of Materials | 250 |
73 Fractal Dimensions | 252 |
74 Simulations of ReactionDiffusion Processes Using Cellular Automata | 257 |
75 The Chemistry of Fractal Distributions | 261 |
752 Reactions on Fractal Surfaces | 265 |
Exercises | 268 |
SYNTHESIS OF INORGANIC MATERIALS | 271 |
82 Solid State Reactions | 280 |
83 Synthesis from Liquids | 282 |
832 Liquid Salts as Solvents | 284 |
833 Hydrothermal Processes | 289 |
834 SolGel Method | 291 |
84 Gas Phase Techniques | 295 |
842 Physical Vapor Deposition | 298 |
843 Chemical Vapor Deposition | 300 |
844 Plasma Synthesis | 310 |
Exercises | 313 |
References | 314 |
317 | |
92 Requirements and Constraints | 320 |
93 Combination Properties of Composites | 324 |
931 Sum Properties | 325 |
932 Product Properties | 327 |
933 Morphology | 328 |
94 Functional Materials | 329 |
941 Thermistors | 331 |
942 Varistors | 333 |
943 Active Materials | 334 |
95 Fabrication of Composites | 338 |
Exercises | 340 |
References | 342 |
INORGANIC PHYSICAL CHEMISTRY | 343 |
102 Equilibrium Thermodynamics | 344 |
103 Defect Chemistry | 352 |
Intrinsic Defect Concentrations | 354 |
Extrinsic Defect Concentrations | 355 |
Gas Equilibria | 356 |
7034 Defect Reactions | 360 |
104 Diffusion in Solids | 366 |
105 A Note on Diffusion Coefficients | 375 |
Exercises | 377 |
References | 378 |
INDEX | 379 |
Άλλες εκδόσεις - Προβολή όλων
The Inorganic Chemistry of Materials: How to Make Things out of Elements Paul J. van der Put Περιορισμένη προεπισκόπηση - 2013 |
The Inorganic Chemistry of Materials: How to Make Things out of Elements Paul J. van der Put Δεν υπάρχει διαθέσιμη προεπισκόπηση - 2013 |
The Inorganic Chemistry of Materials: How to Make Things out of Elements Paul J. van der Put Δεν υπάρχει διαθέσιμη προεπισκόπηση - 2013 |
Συχνά εμφανιζόμενοι όροι και φράσεις
agglomerate atomic orbitals bandgap borides boron carbide carbon catalysts cations ceramics charge Chemical Bond Chemistry of Materials clusters coefficient colloidal complexes components composite compounds concentration conductivity conductors constant coordination corrosion covalent bonds crystallite defects depends deposition determined diffusion dimension driving forces electric electron holes electronegativity equilibrium example Figure formation fractal gas phase glass grain boundaries growth heat high temperatures hydrogen increases inert Inorganic Chemistry Inorganic Materials interatomic intermetallic interstitial ionic kinetics lattice layer ligands liquid magnetic mechanical metal atoms metal ion microstructure mixture mobility molecular molecules morphology nitride nucleation optical orbitals oxide oxygen p-type parameters particles phase diagram phase transitions physical plasma polymers potential powder precursors pressure properties react reactants reaction rate reactive reactor semiconductors sensor silicon single crystals sintering Solid State Chemistry solid state reactions solution solvent stoichiometry substrate surface reaction symmetry synthesis thermal thermodynamic transition metal types vacancies valence electrons vapor