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ON PHYSICS OR NATURAL PHILOSOPHY.

No. XV.

CAPILLARY ATTRACTION.

(Continued from page 205.)

Effect of Curvature on Capillary Phenomena.-On the concave or convex form of the meniscus depend the ascent or depression of a liquid in a capillary tube. For example, since, by the preceding statements, the liquid particles of a concave meniscus a b c d, fig. 57, are kept in equilibrium by the forces which act upon them, they exert no attraction on the lower layers of the liquid; but they act, in consequence of molecular attraction, on the layers nearest to them; whence it follows that upon any layer mn, situated in the interior of the tube, the pressure is less than if there had been no meniscus. Conse quently, according to the conditions of the equilibrium of a liquid mentioned in a former lesson, the liquid must rise in the tube until the interior pressure on the layer m n be equal to the pressure represented by op, which acts exteriorly on any point p of the same layer.

Cause of the Curvature of Liquids in Contact with Solids.-The differences in the form of the surface of a liquid in contact with a solid body, arise from the differences in the ratio which exists between the attraction of the solid for the liquid, and of the attraction of the liquid for itself. Suppose, for instance, that a liquid particle m, fig. 54, is in contact with a solid body. This particle is under the action of three forces; viz., 1st, gravity, which attracts it in the vertical direction m P, 2nd, the attraction of the liquid itself, which acts in the direction In the case of the liquid particles of a convex meniscus, m F, and 3rd, the attraction of the solid which acts in the direc-ghik, fig. 58, the equilibrium still exists, in consequence of tion mn. Now, according to the intensities of these forces, their resultant will take the three following positions, figs. 54, 55, and 56:

Fig. 58.

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1st, fig. 54. When F, the attraction of the liquid to itself, is double of n, the attraction of the solid to the liquid, the direction of the resultant m R, coincides with that of gravity m P; and the surface of the liquid at m is horizontal; for, according to the condition of equilibrium in liquids, formerly explained, their surface must be perpendicular to the direction of m R, that force which acts upon their particles.

2nd, fig. 55. When F, the attraction of the liquid to itself, is less than the double of n, the attraction of the solid to the liquid, that is, when the force n increases, or the force F diminishes, the direction of the resultant mR is within the angle n m P, and the surface takes a direction perpendicular to that of the resultant; whence it becomes concave.

3rd, fig. 56. When F the attraction of the liquid to itself is greater than double of n, the attraction of the solid to the liquid, that is, when the force F increases and the force n diminishes, the direction of the resultant R is within the angle P MF, and the surface takes a direction perpendicular to that of the esultant; whence it becomes convex.

VOL. IV.

Fig. 57.

the molecular forces which act upon the liquid; but the capillary action of the particles which occupy this space being counteracted, they no longer act upon the lower particles. From this it follows, that the pressure on any layer m n, situated in the interior of the tube, is greater than if the space ghik were full of liquid, for the molecular forces which act within it are more intense than that of gravity. The liquid must therefore sink in the tube until the interior pressure on the layer mn, be the same as that at any point q of this layer, exterior to the tube.

Cause of the Attraction and Repulsion of light Bodies floating in a Liquid.-We have seen in a former lesson, that the light bodies which float on the surface of water, and which are wetted by that liquid, are drawn towards each other whenever the distance between them is sufficient to admit of capillary action. The same effect is produced between two light bodies which are not wetted by the liquid. And if the liquid wets the one body and not the other, they exhibit a repulsion, which prevents their contact. The following is the explanation of these three cases.

1st, fig. 59. When two plates of glass are immersed in water, parallel and near to each other, they have a tendency to meet;

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for if the line of liquid level M N be drawn, every portion of liquid situated above this level is raised in consequence of an attraction which acts upon it.

Now it is evident that on the exterior face of the plate A, the active portion of the attracted liquid rises only to the point p, whilst on the interior face of the same plate this portion rises to q. There is therefore a predominating force, which by its surplus of intensity tends to draw the plate A on this side, towards the plate B, and if it were free it would move in that direction; in like manner, the force indicated by the difference 93

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of level between q' and'p', would cause the plate в to move at the instant when the liquid has reached the top of the tube, towards the plate a. its upper surface changes from concave to convex, and conse · 2nd. fig. 60. When the plates of glass are immersed in mer-quently the pressure becoming greater than if the surface were cury, this liquid assumes the form shown in this figure, as plane, the ascensional motion is arrested.

Fig. 60. A B

formerly indicated. Now it is evident, according to the laws of the equilibrium of liquids, that in the case of the plate A, the mercury rising on the one side to p and on the other side to g, its exterior face is more powerfully urged or pushed than its interior face, and that in consequence of this difference of pressure the plate a must be pushed towards the plate B. The phenomenon being symmetrical for the plate B, it is in like manner pushed or urged towards the plate ▲.

3rd. fig. 61. When the plates of glass are such, that on immersion, the one, a, is wetted by the water, and the other, B, Fig. 61.

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being rubbed over with grease, is not wetted, then, in consequence of the latter cause, the plate в depresses the level between the plates, and the liquid rises only to g on the adjacent side of the plate a, whereas it rises top on the other side; whence, the difference of these attracting forces, measured by the difference of level between p and q, will occasion a separation between the plates. Conversely, in consequence of the attraction of the plate A, which raises the level between the plates, the liquid will only sink to q' on the adjacent side of the plate B, whereas it sinks to qon the other side; whence, the difference of the pressure of these forces, measured by the difference of level between p' and q', will occasion as before a separation between the plates; and thus the mutual repulsion of the plates, on account of both causes, will be the result.

The theory of capillary action, one of the most difficult in Natural Philosophy, can only be treated fully and completely by the aid of mathematical analysis; and thus has it actually been investigated by the most eminent mathematicians of modern times, especially by MM. Clairault, Laplace, and Poisson.

Curious Facts relating to Capillary Action-When a capillary tube is immersed in a liquid which wets it, we find that if we withdraw the tube with care, the liquid column which remains suspended in the tube is greater than that which rose in that the tube draws after it a drop of liquid which adheres to that the tube draws after it a drop of liquid which adheres to its lower part, and there forms a convex meniscus whose action unites with that of the concave meniscus at the top, and thereby supports a greater column.

it when the tube was immersed. The reason of this is

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For a similar reason, when a capillary tube is immersed in a liquid, no issue takes place, although the tube be shorter than the liquid column which would rise in it were it longer. For

Capillary action is the cause of oil rising in the wicks of lamps, of the imbibition (drinking in) of liquids in wood, in sponges, and generally in all bodies which are sensibly

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porous.

LESSONS IN BOOKKEEPING.-No. XIL THE LEDGER.

(Continued from page 200.)

We have already said so much on the Ledger, and the manner of posting the Journal into it, in Lesson VI., p. 339, vol. III., that we have now only to refer our students to that Lesson again for the proper explanations, before commencing the study of the Ledger. We shall here, however, repeat emphatically what was there taught in another form, in order to impress their minds with the simplicity of the method of keeping Books by Double Entry.

When an entry in the Journal contains only a single Dr. and this has been explained at p. 341, vol. III. When an entry a Single Cr., the rule is to Debit the Dr. and Credit the Cr.; in the Journal contains a single Dr. and a number of Crs., included in the word Sundries, the rule is to Debit the Dr. and Credit each of the Crs. When an entry in the Journal contains a number of Drs., included under the word Sundries, and and a single Cr., the rule is to Debit each of the Drs. and Credit the Cr. Now, as nothing can be more simple than these rules, we proceed to explain the method of striking a General Balance, that is, of finding out a Merchant's Assets and Liabilities, and consequently whether he has gained or lost by trade.

In commencing the process of balancing the Ledger by Double Entry, the first thing is to close up all accounts in it, of which the two sides, Dr. and Cr., when added up, are perfectly equal, or balanced by the settlement of account. This will generally be the case in a great number of the personal accounts at the end of a given period, say the close of the year, or at Midsummer. To close up such accounts is merely to add up the sums on each side, to draw lines under the sums exactly opposite each other, to put down the totals, and to draw lines under them also. If there be any space left in the folio under an account thus closed, it may be used for the entries of new transactions under the same account, or with the same party.

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All the self-balancing accounts being closed up, the Trial Balance is now to be made out; this consists of a list of all the unbalanced accounts in the Ledger, with the total sums of all the entries on each side inserted in Dr. and Cr. columns, for the purpose of easy reference in making out the General Balance, and for the immediate object of ascertaining the accuracy of all the entries in the Ledger. The latter object is at once obtained by adding up both sides of the Trial Balance, viz., the Dr. side and the Cr. side; for if the sum of both sides be the same, the strong presumption is, that the Ledger is correct; and, of course, the Journal, and all the subsidiary Books, equally so. We say the strong presumption only, because there sometimes occurs in a Ledger such a thing as a balance of errors, that is, when a wrong entry on the Dr. side of the Ledger is balanced by a wrong entry of the same amount on the Cr. side.

In Balancing the Books, as the phrase is, very great trouble is Entry, in consequence of the admission into the Ledger of all saved in making out the Balance Sheet and Check by Double the Property and Profit and Loss Accounts, and indeed of every this process, as shown at the end of the Journal, in our last account in any manner affecting the business. In conducting lesson, two new accounts are opened in the Ledger, the one being called Balance Account, which is to be considered the converse of Stock Account as to its Dr. and Cr. sides; for on the Dr. side are contained all the Assets, and on the Cr. side all the Liabilities; the other being called The Profit and Loss Account, which ontains on the Dr. side the amount of all the Losses experienced in business, and on the Cr. side the amount of all the Gains. By means of these two accounts, all the unclosed accounts in

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